Fumarolic emissions from Mount St. Augustine,Alaska: 1979–1984 degassing trends,volatile sources and their possible role in eruptive style     

Lawrence G Kodosky  Roman J Motyka  Robert B Symonds 《Bulletin of Volcanology》1991,53(5):381-394

Gas samples were collected from high-temperature, rooted summit vents at Mount St. Augustine in 1979, 1982, and 1984. All of the gas samples exhibit various degrees of disequilibrium. Thermodynamic restoration of the analyzed gases permits partial or complete removal of these disequilibrium effects and allows inference of equilibrium gas compositions. Long-term (1979–1984) degassing trends within resampled or adjacent vents are characterized by increases (from 97.4 to 99.8 mole%) in the H₂O fraction and major decreases in the residual gases. Over this same period total gas HCl contents decreased by a factor of 3 to 10 while dry gas (H₂O-free recalculated) HCl contents increased by a factor of 1.6 to 3. Dry gas mole proportions at these sites changed from being CO₂-dominated (46% CO₂, 24% H₂ in 1979) to H₂-dominated (49% H₂, 22% CO₂ in 1984). The overall trends in gas chemistry and the stable isotope patterns in gases and condensates from the summit fumaroles can be explained by progressive magmatic outgassing coupled with increasing proportions of seawater in the fumarole emissions.Studies of the gaseous emissions following the 1976 and 1986 Mount St. Augustine eruptions confirmed the Cl- and S-rich nature of the Mount St. Augustine emanations. Seawater, possibly derived from magmatic assimilation or dehydration of near-surface seawater-bearing sediments, could supply a portion of the outgassed Cl and S. Continued seawater influx through subvolcanic fractures or permeable sediments would recharge the seawater-depleted zone and provide a near-surface Cl and S source for the next eruptive cycle,Various lines of evidence support a phreatomagmatic component in the 1976 and 1986 Mount St. Augustine eruptions. We suggest that seawater may interact with magma or volcanic gases during the early explosive phase of Mount St. Augustine eruptions and that it continues to influence high-temperature fumarole emissions as the volcanic system cools.  相似文献   

Iron ore of the Lahn-Dill type formed by diagenetic seeping of pyroclastic sequences — a case study on the Schalstein section at Gänsberg (Weilburg)     

Heiner Flick  H. Dieter Nesbor  Roman Behnisch 《International Journal of Earth Sciences》1990,79(2):401-415

Investigations on the reconstruction of processes and facies relationships from submarine volcanics of Devonian age in the Lahn syncline (Rhenish Mountains, Western Germany) reveal a complex development of secondary alteration. This is well illustrated by a mafic pyroclastic sequence (»Schalstein«) at the Gänsberg near Weilburg where alteration processes are visible by petrographic and geochemical means and can be further classified by cathodoluminescence. Iron ore formation of Lahn-Dill type is recognized as part of this alteration process, resulting from diagenetic seeping. Until recently a direct magmatic source for the Lahn-Dill type iron ore has been the generally accepted model. These bodies have therefore been viewed as a rather unique stratiform deposit, whose occurrence was virtually confined to this type area. However, it is here considered that the formation of the iron ore corresponds well with existing models of alteration processes within recent oceanic environments which are of a more universal occurrence.

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Zusammenfassung Untersuchungen zur Rekonstruktion der Abläufe an und in den submarinen Vulkangebäuden des Devons (Givet/Adorf-Phase) der Lahnmulde (südliches Rheinisches Schiefergebirge) schließen die sekundäre Alteration mit ein und werden an dem ausschließlich aus basischen Pyroklastiten (Schalstein) aufgebauten Profil am Gänsberg bei Weilburg exemplarisch vorgestellt. Diese anhand petrographischer und geochemischer Kriterien erkennbaren sekundären Prozesse zeigen eine mehrphasige Entwicklung auf, die durch Kathodenlumineszenz-Untersuchungen der Karbonatzemente bestätigt und zeitlich geordnet werden kann. Die an die pyroklastische Abfolge gebundene Roteisensteinvererzung vom Lahn-Dill-Typ läßt sich mit der bei diesen Vorgängen erfolgten Wanderung verschiedener Elemente korrelieren. Damit wird die Vererzung zu einem Produkt der diagenetischen Alteration und nicht der magmatischen Differentiation, wodurch sie mit rezent im ozeanischen Raum beobachteten Prozessen vergleichbar ist. Diese Vorstellungen fügen die Lahn-Dill-Erze in aktualistisch begründete Modelle zur Genese von Erzen ein. Damit erscheint die Besonderheit und fast nur auf den rhenoherzynischen Raum beschränkte Verbreitung dieses Typus hinfällig.

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Résumé L'étude de la succession des phénomènes et des relations facielles dans les volcanites sous-marines d'âge dévonien du synclinal de la Lahn (Massif schisteux rhénan) fait apparaître des processus complexes d'altération secondaire. Ceci est particulièrement bien illustré par la séquence pyroclastique («Schalstein») du Gänsberg près de Weilburg: les processus secondaires, identifiables par des critères pétrographiques et géochimiques y présentent un développement polyphasé dont l'histoire peut être reconstituée par application de la cathodo-luminescence au ciment carbonaté. Les minéralisations en fer associées à la série pyroclastique peuvent être corrélées avec les migrations de divers éléments impliqués dans ces processus. Ces minéralisations apparaissent ainsi comme le produit d'une altération diagénétique et ne correspondent donc pas au modèle généralement admis d'une différenciation magmatique. Cette genèse par altération est d'ailleurs conforme à ce qu'on observe dans les domaines océaniques récents de sorte que les gisements de la région Lahn-Dill doiventêtre considérés non pas comme une singularité du massif schisteux rhénan, mais comme l'expression d'un phénomène plus général à caractère actualiste.

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Lightning climatology in Colombia     

Diaz  Fernando  Ortiz  Diego  Roman  Francisco 《Theoretical and Applied Climatology》2022,149(1-2):69-82

Theoretical and Applied Climatology - Colombia’s lightning climatology was studied using 16 years of high-resolution data from the Tropical Rainfall Measuring Mission Lightning Imaging Sensor...  相似文献   

Walking algorithms for point location in TIN models     

Roman Soukal  Martina Málková  Ivana Kolingerová 《Computational Geosciences》2012,16(4):853-869

Finding which triangle in a planar or 2.5D triangle mesh contains a query point (so-called point location problem) is a frequent task in geosciences, especially when working with triangulated irregular network models. Usually, a large number of point locations has to be performed, and so there is a need for fast algorithms having minimal additional memory requirements and resistant to changes in the triangulation. So-called walking algorithms offer low complexity, easy implementation, and negligible additional memory requirements, which makes them suitable for such applications. In this article, we focus on these algorithms, summarize, and compare them with regard to their use in geosciences. Since such a summary has not been done yet, our article should serve those who are dealing with this problem in their application to decide which algorithm would be the best for their solution. Moreover, the influence of the triangulation type on the number of the visited triangles is discussed.  相似文献   

In situ methods for measuring thermal properties and heat flux on planetary bodies   总被引：1，自引：0，他引：1  

Kömle NI  Hütter ES  Macher W  Kaufmann E  Kargl G  Knollenberg J  Grott M  Spohn T  Wawrzaszek R  Banaszkiewicz M  Seweryn K  Hagermann A 《Planetary and Space Science》2011,59(8):639-660

The thermo-mechanical properties of planetary surface and subsurface layers control to a high extent in which way a body interacts with its environment, in particular how it responds to solar irradiation and how it interacts with a potentially existing atmosphere. Furthermore, if the natural temperature profile over a certain depth can be measured in situ, this gives important information about the heat flux from the interior and thus about the thermal evolution of the body. Therefore, in most of the recent and planned planetary lander missions experiment packages for determining thermo-mechanical properties are part of the payload. Examples are the experiment MUPUS on Rosetta's comet lander Philae, the TECP instrument aboard NASA's Mars polar lander Phoenix, and the mole-type instrument HP³ currently developed for use on upcoming lunar and Mars missions. In this review we describe several methods applied for measuring thermal conductivity and heat flux and discuss the particular difficulties faced when these properties have to be measured in a low pressure and low temperature environment. We point out the abilities and disadvantages of the different instruments and outline the evaluation procedures necessary to extract reliable thermal conductivity and heat flux data from in situ measurements.  相似文献   

The effect of alkalis and polymerization on the solubility of H<Subscript>2</Subscript>O and CO<Subscript>2</Subscript> in alkali-rich silicate melts     

Francesco?VetereEmail author  Francois?Holtz  Harald?Behrens  Roman?E.?Botcharnikov  Sara?Fanara 《Contributions to Mineralogy and Petrology》2014,167(5):1014

The effect of alkalis on the solubility of H₂O and CO₂ in alkali-rich silicate melts was investigated at 500 MPa and 1,250 °C in the systems with H₂O/(H₂O + CO₂) ratio varying from 0 to 1. Using a synthetic analog of phonotephritic magma from Alban Hills (AH1) as a base composition, the Na/(Na + K) ratio was varied from 0.28 (AH1) to 0.60 (AH2) and 0.85 (AH3) at roughly constant total alkali content. The obtained results were compared with the data for shoshonitic and latitic melts having similar total alkali content but different structural characteristics, e.g., NBO/T parameter (the ratio of non-bridging oxygens over tetrahedrally coordinated cations), as those of the AH compositions. Little variation was observed in H₂O solubility (melt equilibrated with pure H₂O fluid) for the whole compositional range in this study with values ranging between 9.7 and 10.2 wt. As previously shown, the maximum CO₂ content in melts equilibrated with CO₂-rich fluids increases strongly with the NBO/T from 0.29 wt % for latite (NBO/T = 0.17) to 0.45 wt % for shoshonite (NBO/T = 0.38) to 0.90 wt % for AH2 (NBO/T = 0.55). The highest CO₂ contents determined for AH3 and AH1 are 1.18 ± 0.05 wt % and 0.86 ± 0.12 wt %, respectively, indicating that Na is promoting carbonate incorporation stronger than potassium. At near constant NBO/T, CO₂ solubility increases from 0.86 ± 0.12 wt % in AH1 [Na/(Na + K)] = 0.28, to 1.18 ± 0.05 wt % in AH3 [Na/(Na + K)] = 0.85, suggesting that Na favors CO₂ solubility on an equimolar basis. An empirical equation is proposed to predict the maximum CO₂ solubility at 500 MPa and 1,100–1,300 °C in various silicate melts as a function of the NBO/T, (Na + K)/∑cations and Na/(Na + K) parameters: \({\text{wt}}\% \;{\text{CO}}_{2} = - 0.246 + 0.014\exp \left( {6.995 \cdot \frac{\text{NBO}}{T}} \right) + 3.150 \cdot \frac{{{\text{Na}} + {\text{K}}}}{{\varSigma {\text{cations}}}} + 0.222 \cdot \frac{\text{Na}}{{{\text{Na}} + {\text{K}}}}.\) This model is valid for melt compositions with NBO/T between 0.0 and 0.6, (Na + K)/∑cation between 0.08 and 0.36 and Na/(Na + K) ratio from 0.25 to 0.95 at oxygen fugacities around the quartz–fayalite–magnetite buffer and above.  相似文献   

Eutrophication of a Maryland/Virginia Coastal Lagoon: a Tipping Point,Ecosystem Changes,and Potential Causes     

Patricia M. Glibert  Deborah C. Hinkle  Brian Sturgis  Roman V. Jesien 《Estuaries and Coasts》2014,37(1):128-146

Water quality in the Maryland/Virginia Coastal Bays has been declining for many years from anthropogenic inputs, but conditions appear to have worsened abruptly following a shift from long-term dry to long-term wet conditions in the early 2000s. Annually and regionally averaged total nitrogen concentrations are approximately twofold higher, but ammonium (NH₄ ⁺) concentrations are up to an order of magnitude higher than in the early 1990s. Averaged nitrate concentrations, however, changed to a lesser degree throughout the time course; water column concentrations remain very low. Total phosphorus has only increased in some bay segments, but increases in phosphate (PO₄ ^3?) have been more pervasive. There were differences in the year in which large increases in each nutrient were first noted: PO₄ ^3? in ~2001–2002, followed by NH₄ ⁺ ~a year later. The effects of a combination of steadily increasing anthropogenic nutrient increases from development, superimposed on nutrient loads from farming and animal operations, and groundwater inputs were accelerated by changes in freshwater flow and associated, negatively reinforcing, biogeochemical responses. Regionally, chlorophyll a concentrations have increased, and submersed aquatic vegetation has decreased. The system is now characterized by sustained summer picoplanktonic algal blooms, both brown tide and cyanobacteria. The retentive nature of this coastal lagoon combined with the reducing nature of the system will make these changes difficult to reverse if the current dual nutrient management practices are not accelerated.  相似文献   

A family of zero-velocity curves in the restricted three-body problem     

R. Roman  I. Szücs-Csillik 《Astrophysics and Space Science》2014,352(2):481-491

The equilibrium points and the curves of zero-velocity (Roche varieties) are analyzed in the frame of the regularized circular restricted three-body problem. The coordinate transformation is done with Levi-Civita generalized method, using polynomial functions of n degree. In the parametric plane, five families of equilibrium points are identified: \(L_{i}^{1}, L_{i}^{2}, \ldots, L_{i}^{n}\) , \(i\in\{ 1,2,\ldots,5 \}, n \in\mathbb{N}^{*}\) . These families of points correspond to the five equilibrium points in the physical plane L ₁,L ₂,…,L ₅. The zero-velocity curves from the physical plane are transformed in Roche varieties in the parametric plane. The properties of these varieties are analyzed and the Roche varieties for n∈{1,2,…,6} are plotted. The equation of the asymptotic variety is obtained and its shape is analyzed. The slope of the Roche variety in \(L_{1}^{1}\) point is obtained. For n=1 the slope obtained by Plavec and Kratochvil (1964) in the physical plane was found.  相似文献   

Agricolaite, a new mineral of uranium from J��chymov, Czech Republic     

Roman Sk��la  Petr Ondru?  Franti?ek Veselovsky  Ivana C��sa?ov��  Jan Hlou?ek 《Mineralogy and Petrology》2011,103(1-4):169-175

The new mineral agricolaite, a potassium uranyl carbonate with ideal formula K₄(UO₂)(CO₃)₃, occurs in vugs of ankerite gangue in gneisses in the abandoned Giftkiesstollen adit at Jáchymov, Czech Republic. The name is after Georgius Agricola (1494?C1555), German scholar and scientist. Agricolaite occurs as isolated equant irregular translucent grains to 0.3?mm with yellow color, pale yellow streak, and vitreous luster. It is brittle with uneven fracture and displays neither cleavage nor parting. Agricolaite is non-fluorescent. Mohs hardness is ~4. It is associated with aragonite, brochantite, posnjakite, malachite, rutherfordine, and ??pseudo-voglite??. Experimental density is higher than 3.3?g.cm^?3, Dcalc is 3.531?g.?cm^?3. The mineral is monoclinic, space group C2/c, with a 10.2380(2), b 9.1930(2), c 12.2110(3) ?, ?? 95.108(2)°, V 1144.71(4) ?³, Z?=?4. The strongest lines in the powder X-ray diffraction pattern are d(I)(hkl): 6.061(55)(002), 5.087(57)(200), 3.740(100)(202), 3.393(43)(113), 2.281(52)(402). Average composition based on ten electron microprobe analyses corresponds to (in wt.%) UO₃ 48.53, K₂O 31.49, CO₂(calc) 22.04 which gives the empirical formula K_3.98(UO₂)_1.01(CO₃)_3.00. The crystal structure was solved from single-crystal X-ray diffraction data and refined to R ₁?=?0.0184 on the basis of the 1,308 unique reflections with F _o?>?4??F _o. The structure of agricolaite is identical to that of synthetic K₄(UO₂)(CO₃)₃ and consists of separate UO₂(CO₃)₃ groups organized into layers parallel to (100) and two crystallographically non-equivalent sites occupied by K⁺ cations. Both the mineral and its name were approved by the IMA-CNMNC.  相似文献   

Compaction-formed platy limestone from the Middle Cambrian Zhangxia Formation (Western Hills,China): towards a new classification for bedded limestone     

Guangzhen Chu  Roman Koch  Christian Weiss 《Swiss Journal of Geoscience》2011,104(1):5-19

Remarkable bedding features occur in Middle Cambrian platy limestone of the Western Hills close to Beijing in NE-China, which are intercalated in a sequence of shallow water carbonates (mudstones, storm deposits, oolitic grainstones). The platy limestone beds (up to 5 cm thickness) have undergone complex diagenetic compaction and pressure solution. Varying facies types are characterized by wavy, stylolitic boundaries with different thickness of clay accumulation and common lateral pinch out. Cross-cutting relationships of stylolites commonly destroy primary bed-surfaces. This indicates an intimate interfingering resulting in an indenting fabric of primary separated facies types. Nevertheless, primary sedimentary boundaries can be recognized. There occur varying types of compaction features documented by different stylolite types with varying amplitudes and thickness of clay-enrichments (parallel clay seams, stylolamination, stylo-nodular and stylo-brecciated structures with multi-grained seams). Bedded limestone of the type documented, generally belong to the limestone family of Plattenkalk, Lithographic Limestone or platy limestone, which can form in different environments. Consequently, using these names without detailed data on some specific parameters (e.g. thickness, surface morphology, composition of allochems, particle and crystal size) results in more confusion and hinders the comparison of Plattenkalk, Lithographic Limestone and platy limestone from different locations throughout the earth history. Therefore, a classification is proposed here which is based on macroscopic, microscopic, and sub-microscopic parameters. Plattenkalk and platy limestone are considered to form the two main groups. Plattenkalk beds are laterally consistent and have parallel, horizontal surfaces. Platy limestone can pinch out laterally and reveals irregular and inclined bed surfaces. Single beds in both can have different thickness, internal structure (e.g. micritic, microsparitic) and fabric (e.g. homogeneous, nodular), particle content and other variations (e.g. chemical, mineralogical). These parameters should be added to the basic name and used in a system similar to Folk’s limestone classification. Lithographic Limestone is defined as a subgroup of Plattenkalk with well-defined parameters. A consequent use of this classification will also help to understand fossil preservation and/or non-preservation in different types of Plattenkalk, Lithographic Limestone, and platy limestone.  相似文献